Aired: 9/10/1966
The Bubbler kidnaps the Shah of Shish-Ka-Bob and it's up to the Impossibles to rescue the Shah.
The Spinner steals a $1,000,000 tiara.
Aired: 9/17/1966
The Paper Doll Man has stolen a top secret plan and is out to steal the second part.
Beamatron steals a priceless painting from a ship.
Aired: 9/24/1966
The Burrower uses his burrowing machine to steal half a million dollars from the bank and dig ten miles down to his lair.
Timeatron uses his time cabinet to bring villains from the past to pillage for him.
Aired: 10/1/1966
Smogula freezes the Impossibles and seals them within a cave, so they will not interfere with his plans to conquer Empire City.
The Speck uses a formula to shrink himself in order to photograph top secret plans.
Aired: 10/8/1966
To get the Impossibles out of the way, Fero uses his fiddle to transport them to different planets.
Mother Gruesome invents a machine that brings villainous storybook characters out of their stories to help her with her crimes.
Aired: 10/15/1966
Televisatron transports the Impossibles to different television shows.
The Dauber uses a special brush where anything he paints becomes real.
Aired: 10/22/1966
Aquator has stolen a secret formula from a scientist who is friends with Big D and shrinks himself to microscopic size in order to get all the microscopic creatures to become large.
Professor Stretch causes havoc with his elastic abilities.
Aired: 10/29/1966
The Dragster has stolen a valuable item.
The Spinner returns and steals a priceless pooch.
Aired: 11/5/1966
The Surfer takes pictures of a top secret submarine.
The Puzzler steals top secret documents.
Aired: 11/12/1966
Spraysol steals top secret documents.
The Sculptor turns people into statues.
Aired: 11/19/1966
The Archer steals a priceless violin and a million dollars.
Aired: 11/26/1966
The Inflator creates giant balloon monsters to help him commit crimes.
The Diamond Dazzler steals a precious diamond in order to awaken the genie within.
The Paper Doll Man returns and causes trouble.
Aired: 12/3/1966
A witch named Cronella Critch robs a charity for orphans party.
The Twister is stealing precious jewels.
Aired: 12/10/1966
Professor Stretch returns and creates a rubber monster to help him.
The Tapper transmits himself over phone lines.
Aired: 12/17/1966
The Angler steals secret space research.
The Ringmaster puts on a circus and robs from those who attend.
Aired: 12/24/1966
Billy the Kidder is a cowboy who rides a robotic horse and plans to rob the U.S. Mint.
Dr. Futuro comes from the 40th century to the twentieth century to steal a million dollar gold brick.
Aired: 12/31/1966
The Clutcher uses an invention that brings his gloves to life.
Mr. Instant uses his insta-gun that can make anything in an instant.
Aired: 1/7/1967
The Batter kidnaps a baseball star and holds him for ransom.
Mr. Ice and his henchman Freezer Freezer freeze the city in order to take it over.